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Mixture calculations employ a model that applies mixing rules to the Helmholtz energy of the mixture components it uses a departure function to account for the departure from ideal mixing. It implements three models for the thermodynamic properties of pure fluids: equations of state explicit in Helmholtz energy, the modified Benedict-Webb-Rubin equation of state, and an extended corresponding states (ECS) model. REFPROP is based on the most accurate pure fluid and mixture models currently available. The equations are generally valid over the entire vapor and liquid regions of the fluid, including supercritical states the upper temperature limit is usually near the point of decomposition of the fluid, and the upper pressure (or density) limit is defined by the melting line of the substance. Their high accuracy is obtained through many coefficients in the equations, and thus the calculation speed will be slower than other equations such as the Peng-Robinson cubic equations. 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